When you use the phrases "has been " or "have been" it shows a continuous action . So you are still doing that action . So " I have been busy this week " shows the speaker that you were busy the previous days and you still are busy even now .
When you use the words "was" and "were " it shows past actions. Remember that these words are the past actions of "is " and "are" and in some cases "am" .
"I was busy this week", shows that this week you were busy but not anymore .