"As of yet" means the same thing as "as of now"; however, "as of yet" is usually used in the negative sense.
"As of yet, he hasn't started."
"As of yet, we've received no information."
"As of now" can be used both in the positive and negative sense:
"As of now, we have completed 50% of the project."
"As of now, we have 134 members."
It should also be noted that "as of yet" would normally be used in more formal writing and speech. In every day speech, you would more likely hear just "yet":
"He hasn't started yet."