My brother and I. That is good grammar. It is because "I" is used for the subject of a sentence. "Me" is only used as an object. "Give the ball to me". "Don't hit me." "Leave me alone". So if you knock on a door and someone says "Who is there?" you would say "It is I." Do not say "It is me." or "Me." If you do then people will think you are uneducated, and you are showing that you are willing to become educated.