definite / definitive. The first just means 'certain'. the second has some other meanings. You can apply it as an adjective to something, that gives the thing a quality of 'defining' the class of thing. E.g. He delivered the definitive lecture on the subject'
For / toward: The first means something has been assigned for a purpose. This is a jacket for your brother. The second implies a direction of movement or purpose. 'He threw the jacket towards his brother'. Or 'He gave some money towards your education'.
An expert by definition - there is a double meaning here. You are saying, that he is so expert that one could use his example to define the meaning of 'expert'. The second meaning then, is saying that as the term 'expert' has been defined, he clearly and measurably matches the definition. It means both things at the same time. It is really a superlative.