1.in meaning: 别的is usually used in general sense, but 另外的makes a particular reference. 我只要一杯水，别的不要了。 我只要一个苹果，另外的几个你们吃吧。 2.in collocation: 别的can not be used with numeral-classifier compounds but 另外的 can be used both on singular or plural 另一个 另外几个 3.in function: 别的 can be use as subject but 另外的only can be subject when it collocate with the measuring word. 别的都吃了，就剩苹果了。 另一个人吃饱了，你吃吧

别，一般搭配“别的+something or people”, for example 别人，别的东西，the same as "another" ， it also contains another meaning "don't", 别这样，别动任何东西 另，一般搭配“另外”，同“此外”，有转折意思，adv.

别吵了！ Stop making such a noise! 还有别的事情吗？ Anything else? 另外，... What's more, ...

别 another; don't 另 other; another; separate; extra; in addition