When something "smacks" you, it forces you to suddenly to take notice. Usually, things that _force_ you to take notice are negative, but not always. "Smack" is similar to "strike". However, since "strike" is less forceful than "smack", "strike" is used for positive as well as negative things. You could say
"It struck me as odd that people were feeding the alligators."
However, it is not merely "odd" to feed alligators. It is dangerous. "Strike" is not strong enough so you could say instead
"The sheer insanity of feeding the alligators smacked of brainlessness."
"Strike" is often used in a positive way:
"It struck me that he had many talents".
You couldn't use "smack" that way.