Sunday is the first day of a week , so it is No 1. (the boss), but No 1 has been given to 星期一 , according the rules, Tuesday is 星期二 and so on.... Sunday should be called 星期七, and of course it is not proper to call the boss NO .7 , so we have to think another honorablename for 星期天。。。then people think a lot according what Bear234 explained above...more information for you , we also call Sunday 星期日 (日means 天),it is more often used in oral Chinese.