囧 is new coined, which means embarrassment. you can get the meaning from the shape of the 囧, like expression of face when feel embarrassed and sad. this words is similar to 尴尬. while 别扭 ,when you feel uncomfortable or when you feel something is wrong, or not appropriate, you can use it. for example, when you see a girl match the clothes not properly, you may say: 看起来很别扭。