All four words (reject, decline, refuse, spurn) indicate that the actor is saying "No" to something offered or requested.
Of these, "decline" is the softest. It suggests that something was offered or requested but that the actor did not accept the offer or did not grant the request. "decline" can be used with words such as "politely" or "graciously" as in "the girl graciously declined the invitation to dinner".
"Refuse" is stronger and implies a definite negative answer. Words such as "politely" or "graciously" are less appropriate with "refuse". Example: "The king refused to see the emissary of the country that had attacked his borders and instead sent an army to repel the invasion."
A good way to understand "reject" is to know that it comes from Latin and literally means to "throw back". So, now, the actor is not just saying "No" but figuratively "throwing back" what what was offered. Example: "The prime minister rejected the peace proposal as offering far too little in the way of reparations." "The girl rejected the boy's marriage proposal." "The businessman rejected the proposed purchase of his company as being priced too low, considering other recent transactions."
"Spurn" adds a sense of contempt to the actor's action. "Despite the fact that he was handsome and wealthy, the girl spurned the boy's advances because she thought he was arrogant and self-centered." "The prime minister spurned the peace proposal because he knew that the population of his country felt too angered and insulted to consider anything less than total unconditional surrender." "The businessman spurned the offer to purchase his company because he felt that it had not been made in good faith."
Hope that helps.