Because "especially" is an adverb, it should be used accordingly - which is to modify verbs, adjectives, and other adverbs. Furthermore, it is applicable when you either single out something because you like/hate/value/etc. something in a greater extent than others. Think of the word "particularly," since they have similar meanings.
So the sentence, "I especially like reading," is grammatically correct, if you meant that you particularly like reading among other activities that you like (meaning, you singled out reading from the set of activities that you like because you like reading more).
I hope this helps!