"Grow up" is much more specific phrase than the verb "grow." Although "grow up" refers to the process of a child maturing into an adult, you can say to an adult, "Grow up!" In this context, it is used pejoratively, implying that the adult is behaving like a child. (Perhaps this command form is what Will had in mind when he wrote that this phrase is not used with a subject? You wouldn't say "Grow!" to a person...but I could imagine someone who likes to talk to their plants saying it.)
Grow, as a more general word, can refer to lots of types of growth, including emotional, mental or spiritual growth. Also, as a more general word, it can imply a maturation process but not one that involves the change from childhood to adulthood. So here's two examples:
"This experience has made me grow up." This sentences implies that I was immature--or childish--before (even if I was technically an adult), but now I act more like an adult.
"The experience really helped me grow." This sentence can imply that I was a mature adult before, but now my outlook on life/emotional or spiritual awareness/perspectives, etc. have changed or expanded.