Pez= when still in their habitat, so you add the participle "ADO" at the end of the word, it which suggests that the animal has been PescADO or "Catched" in english, so, this word can be used in fishes: "I want Pescado for dinner" but also in people or things: "¡Hey, Look what I Pescado/caught!" or "I had Pescado/caught that guy"
In the chlean Spanish Slang it can also mean "Pay attention"
Oye! pescame! = HEY! Give me your attention!