They're pretty much the same. I think "plush," as Timo said, refers to the material, so a "plush toy" is any toy that is soft, but not necessarily an animal.
"stuffed animal" is more of a description of what it represents and is inside, rather than describing what the external is.
In practice, they are the same item in 99% of the cases, but in theory they could be different. I think that's where the difference lies. :)