when they both means to work
劳动 is more a temporary labour so you can say 今天我在农田劳动 today i work on the farm
工作 is more for you work as a profession like e.g 我在公司工作 i work in a company
2013년 2월 2일
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劳动 is labour work (blue collar)
工作 means to work (mainly white collar)