나로, which is 나(me) + (으)로 (to, for, with), is not used very often, so we need to see the whole phrase.
You might say something like 당신의 선택을 나로 해 주세요 (Make your choice me, please), but it's a rare kind of sentence. We are more likely to say 나를 선택해 주세요 - Please choose me.
나로 can also appear as part of some other expressions, as in
- 나로 인하여/말미암아 - on account of me, because of me.
- 나로 하여금 - causing me (to do something, to end up certain way).
- 나로 말하자면 - speaking of myself.
인하여, 말미암아, 하여금 are all rather formal sounding phrases not used much in conversation.