As to the English sentences you having required, I think you could use the sentences in a dictionary under the words "besides" and “except". I will give u two here below for your practice with "除了...以外” :
1. I think she has many good qualities besides being very beautiful.
我觉得她除了非常漂亮 之外,还有许多好的品质。
2. I wouldn't have accepted anything except a job in New York.
我当时是不会接受一份除了纽约以外任何其他地方的工作的。