Sam,
She is older than me.
She is older than I.
They are both correct. "Than" has been used as both a preposition "than me" and a conjunction "than I" for the last 500 years
Examples from Shakespeare:
-I thank God I am as honest as any man living that is an old man and no honester THAN I.
William Shakespeare - "Much Ado about Nothing", Act 3 scene 1
-A man no mightier THAN THYSELF OR ME.
In personal action, yet prodigious grown
And fearful, as these strange eruptions are.
—"Julius Caesar" 1600 by William Shakespeare.
Examples from modern authors:
-Our consul general here is a Columbus man named
Streeper, about two years younger THAN ME.
—James Thurber, letter, 1 June 1954
. . . someone else who can take it less seriously THAN I.
—Robert Frost, letter, 2 Feb. 1920
You have the same choice that Shakespeare had...you can use one or the other and still be correct.