规则:people discuss together then make a rule for something then we call this rule 规则
for example, 足球规则 比赛规则 etc
规定:
1) as a verb. 公司规定我们必须八点开始工作。 the company provides that we must start working at 8 o'clock
2) as a noun. the group or the boss or the law or police or the school etc makes some rules for all of people, then we call these rules 规定
我们必须在八点开始工作,这是公司的规定。 we must start working at 8 o'clock, this is company's rule.
anyway 规则 represents how something runs. and 规定 represents something that we have to respect.