Better is to pick one of them, start to learn for a year - 18 months, build the language core, then pick the second. It would be less confusing and more effective. Russian and Polish are very similar, so you can confuse them.
I know 2 person who are learning Polish and Russian at the same time. They confuse lots of words. Even if alphabet is different, sounds and some words are similar.
I'm learning now Dutch. It's from the same family as English. My English is not that good, but when I have started with Dutch, English become harder for me. For example, during the lesson I confuse Dutch with English sometimes and it's hard to swich between those two languages.
I can not imagine to learn German and Dutch at the same time, for me the similarity here is the same as between Russian and Polish.