They are very similar in meaning, and can be used in basically the same way. The only difference that I can think of is that "I want to go over my report with you later" can suggest that you are reviewing it again (this isn't the first time they have looked at the report). It isn't always used that way, but it is a possible meaning.
"I want to go through my report" just means you want to look at the report with them, and doesn't say anything about if you have already reviewed it.