The two sentences you provided are essentially the same in terms of meaning. They convey the idea that on Sundays, you enjoy going to the cinema to watch movies. The only difference lies in the word order and structure:
"I like to go to the cinema and watch movies on Sunday."
"On Sunday, I like to go to the cinema and watch movies."
In the first sentence, the main statement is presented first, followed by the specific detail about when this activity takes place. In the second sentence, the time element is presented at the beginning, followed by the main statement. Both constructions are grammatically correct and convey the same meaning, so you can choose the one that flows better or sounds more natural to you.