"Mind you" is usually used for warning a person. Here are some examples:
1. You need to stop acting like a child. You're not in primary school, mind you!
(In this sentence, you use "mind you" in order to warn the person who is acting like a child that he/she needs to stop acting like a child because he/she is not a child anymore.)
2. Stop wasting your money like that! You just lost your job, mind you!