I can't say I've heard it used about the sky.. Most often it's usen when talking about sound, "a muffled scream" = a scream that's concealed/ softened by something, perhaps a pillow. A muffled trumpet. Or if you're concealing something else.
If it's used as an adjective for the sky its meaning is probably derived from this. A "muffled" sky would be soft, grey and free of contours. If it's "muffling" then perhaps it's suggested that it works like a pillow on its surroundings, swallowing life and excitement.