Differing ser from estar is a tough issue in Spanish. It needs some practice but there are a few main rules.
Estar is either used for describing the physical placement of someone or something (Lucía está en la calle Cervantes; los libros de Miguel están en su habitación) or to give a clue about how the person looks like, feels like etc at a precise moment (Estoy cansadísima esta tarde; ¿por qué está tan colorada Angela?).
When the person or object is normally this way, it´s their common feature, we use ser (Dolores es normalmente muy pálida pero hoy está colorada; mi carro es mercedes, es grande y rojo; soy polaca)
It´s a long and tricky topic, I´m pretty sure you´ll find a complete explanation in your language.