You can usually omit "that" when it introduces a noun clause:
I think (that) YOU ARE AN EXCELLENT STUDENT.
I think (that) PARIS IS VERY BEAUTIFUL.
I think( that ) BROCCOLI IS DELICIOUS.
In those sentences, "that" is just an introductory word.
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You may also omit "that" when it is a relative pronoun and the object of the verb:
The book THAT you are reading is interesting. ""that" = the book; it is the object of the verb: You are reading that.
BUT you may NOT omit "that" if it is a relative pronoun and the subject of the verb:
I want the flower THAT is red. "That" = the flower. It is the subject of "is." You cannot omit it, for nobody would say "I want the flower is red."