Generally, we say おなかがすいている、おなかがすいた、おなかがへった, etc for "I'm hungry!".
if you want to use the kanji 飢, it's 飢えている[うえている] though I wouldn't use it in everyday conversation. However, there are cases that you see this kanji on the movie, anime or manga, it means "be hungry for", "be lacking ~ ", not only for food or drink, but also other things.
I hope this was helpful.