Unsatisfactory is to describe an object or situation.
Unsatisfied and dissatisfied are to describe emotions.
How are the two emotions different?
Dissatisfied means you are not happy with the quality/performance/ability of something.
Unsatisfied is often used to show when we haven't had enough of something.
Let's use a meal to show the difference.
If the meal is bad, you would say I am dissatisfied by the food. If it was too small and you are not full you are unsatisfied.
On a practical level, dissatisfied is much more common.