This one is potentially confusing in spoken english, because it's not uncommon for english-speakers to mumble or slur their words so that 'Hi there' sounds like 'Hi dere'. (like you sound when you have the flu).So you might hear someone who sounds like they are saying 'Hi dear.'
In practice I don't think anyone would say 'Hi dear' because 'dear' is a rather formal, old-fashioned term, like darling. So one might say 'Hello dear' or 'Hello darling' but probably not 'Hi dear'
Hi there is a nice greeting, it has a little more enthusiasm and energy than just 'hi'. You can tell that it might have been a greeting in person, maybe with a wave. It is like 'hey there' which is specifically for calling someone's attention. 'Hi there' is a greeting, with a little of the same exhuberance.