The word "estimate" can be used both as a noun and a verb. For example, as a noun, "I will give you an estimate on the amount of time it will take to complete this job". As a verb, "I will estimate the time it will take to complete this job".
"Estimation" is usually used only as a noun. It is the act or process of estimating. For example, "The amount of time it will take to complete this job is approximately 4 hours. This is only an estimation of the time. The job could take longer." or, This is only an estimate of the amount of time.