A pop tart is very sugary, horrible pastry. You put it in the toaster or a microwave to heat it.
"Dibs!" = I get to have it! I claim it!
You say it if you want something that nobody else can definitely claim.
"Look there's a dollar bill on the sidewalk. Dibs!"
In this case, I think the person is joking about wanting the pop tart under the refrigerator - either that, or they are VERY hungry.