Courier and Delivery(man) are not interchangeable. They have different meanings. Deliveryman usually delivers goods (wholesale or retail). ex. Tomorrow I have to be home because the deliveryman is coming with the new furniture I bought. Courier is used in a more official, legal, business, governmental situation. ex. Courier can be a diplomat who delivers messages. It can also be someone who is a runner of contraband (i.e. drug runner). It can also be a member of the armed services who delivers mail, information, supplies, etc. Someone who delivers documents between company offices., etc.